I usually start with the head on these types of balloons and work downwards but with this one I made the upper body first and did the head last. James Bond is made of 9 balloons, I made his shirt with a 350 first and then his jacket and sleeves with 2 x 260, then I added in the legs and feet with a 260 and his belt with a bit of left over from his sleeves.
Next I made his hand and gun, both from 160s, and fixed his other sleeve in his pocket with a bit of dead un-inflated balloon. Finally I made his head from a 260 and added the hair with a 160. In all he took me about an hour, I had to have 2 attempts at the body because the first version didn't look like a jacket.